Lives listing by occupation: politician
- Simcoe, John Graves (born 1752–died 1806), English army officer, colonial administrator, politician, member of Parliament
- Simonde de Sismondi, Jean Charles Léonard (born 1773–died 1842), Swiss politician, economist, political philosopher, university teacher
- Sinclair, Sir John, 1st Baronet Sinclair of Ulbster (born 1754–died 1835), Scottish agriculturalist, politician, member of Parliament
- Sissous de Valmire, Pierre Louis (born 1740–died 1819), French lawyer, politician, author
- Skandalidis, Ioannis (born c. 1775–died 1826), Greek lawyer, politician
- Skeffington, John, 2nd Viscount Massereene (born 1632–died 1695), English politician, member of Parliament, aristocrat
- Skene, Robert (born 1719–died 1787), Scottish army officer, soldier, politician, member of Parliament
- Smith, John (born 1655/1656–died 1723), English politician, civil servant
- Smith, Robert (born 1752–died 1838), English banker, politician
- Smith, William (born 1728–died 1814), American merchant, politician
- Smith, Major William (born 1751–died 1837), American colonist, plantation-owner, army officer, politician
- Smith, William (born 1756–died 1835), English politician, member of Parliament, Nonconformist
- Smith, Lieutenant-colonel William Stephens (born 1755–died 1816), American revolutionary army officer, politician, civil servant
- Smyth, Boyle (died 1662), Irish gentleman, politician, member of Parliament
- Snow, John (flourished 1713–1716), English politician
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