Lives listing by nationality: Scottish
- Smith, Margaret [née Douglas] (born 1694–died 1784), Scottish home-maker
- Smith, William (died 1753), Scottish guardian
- Smollett, Tobias (born 1721–died 1771), Scottish physician, surgeon, sailor, novelist, historian, travel-writer
- Somerville, Mary [née Fairfax] (born 1780–died 1872), Scottish polymath, author, science-writer
- Spalding, Reverend John (born c. 1631–died 1699), Scottish churchman
- Speedy, George (flourished c. 1774), Scottish weaver
- Spence, Keith (died c. 1809), Scottish [unknown occupation]
- Spens, George (flourished c. 1679), Scottish [unknown occupation]
- Spottiswoode, John [junior] (born 1711–died 1793), Scottish laird
- Spottiswoode, John (born 1741–died 1805), Scottish lawyer
- Starkey, George (born 1628–died 1665), Scottish alchemist
- St Clair, Arthur (born 1737–died 1818), Scottish army officer, soldier, colonial governor
- St Clair, Colonel Sir John, 3rd baronet (died 1767), Scottish soldier, army officer
- Stedman, Doctor John (died 1791), Scottish physician, author
- Stephen, John (flourished 1740–1765), Scottish banker, civil servant
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